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Jai Ganesh

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Boron

Boron

Gist

Boron is an extremely valuable mineral and it is used in many products from cookware and medicine to nuclear waste storage and space exploration. Boron compounds are mainly used in borosilicate glass products, but are also used in agriculture, in fire retardants, and in soaps and detergents.

Summary

Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral sodium borate, and the ultra-hard crystals of boron carbide and boron nitride.

Boron is synthesized entirely by cosmic ray spallation and supernovas and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals.

Elemental boron is found in small amounts in meteoroids, but chemically uncombined boron is not otherwise found naturally on Earth.

Several allotropes exist: amorphous boron is a brown powder; crystalline boron is silvery to black, extremely hard (9.3 on the Mohs scale), and a poor electrical conductor at room temperature   electrical conductivity). The primary use of the element itself is as boron filaments with applications similar to carbon fibers in some high-strength materials.

Boron is primarily used in chemical compounds. About half of all production consumed globally is an additive in fiberglass for insulation and structural materials. The next leading use is in polymers and ceramics in high-strength, lightweight structural and heat-resistant materials. Borosilicate glass is desired for its greater strength and thermal shock resistance than ordinary soda lime glass. As sodium perborate, it is used as a bleach. A small amount is used as a dopant in semiconductors, and reagent intermediates in the synthesis of organic fine chemicals. A few boron-containing organic pharmaceuticals are used or are in study. Natural boron is composed of two stable isotopes, one of which (boron-10) has a number of uses as a neutron-capturing agent.

Borates have low toxicity in mammals (similar to table salt) but are more toxic to arthropods and are occasionally used as insecticides. Boron-containing organic antibiotics are known. Although only traces are required, it is an essential plant nutrient.

Details

Boron (B), chemical element, semimetal of main Group 13 (IIIa, or boron group) of the periodic table, essential to plant growth and of wide industrial application.

Element Properties

atomic number  :  5
atomic weight  :  [10.806, 10.821]
melting point  :  2,200 °C (4,000 °F)
boiling point  :  2,550 °C (4,620 °F)
specific gravity  :  2.34 (at 20 °C [68 °F])
oxidation state  :  +3

Properties, occurrence, and uses

Pure crystalline boron is a black, lustrous semiconductor; i.e., it conducts electricity like a metal at high temperatures and is almost an insulator at low temperatures. It is hard enough (9.3 on Mohs scale) to scratch some abrasives, such as carborundum, but too brittle for use in tools. It constitutes about 0.001 percent by weight of Earth’s crust. Boron occurs combined as borax, kernite, and tincalconite (hydrated sodium borates), the major commercial boron minerals, especially concentrated in the arid regions of California, and as widely dispersed minerals such as colemanite, ulexite, and tourmaline. Sassolite—natural boric acid—occurs especially in Italy.

Boron was first isolated (1808) by French chemists Joseph-Louis Gay-Lussac and Louis-Jacques Thenard and independently by British chemist Sir Humphry Davy by heating boron oxide (B2O3) with potassium metal. The impure amorphous product, a brownish black powder, was the only form of boron known for more than a century. Pure crystalline boron may be prepared with difficulty by reduction of its bromide or chloride (BBr3, BCl3) with hydrogen on an electrically heated tantalum filament.

Limited quantities of elemental boron are widely used to increase hardness in steel. Added as the iron alloy ferroboron, it is present in many steels, usually in the range 0.001 to 0.005 percent. Boron is also used in the nonferrous-metals industry, generally as a deoxidizer, in copper-base alloys and high-conductance copper as a degasifier, and in aluminum castings to refine the grain. In the semiconductor industry, small, carefully controlled amounts of boron are added as a doping agent to silicon and germanium to modify electrical conductivity.

In the form of boric acid or borates, traces of boron are necessary for growth of many land plants and thus are indirectly essential for animal life. Typical effects of long-term boron deficiency are stunted, misshapen growth; vegetable “brown heart” and sugar beet “dry rot” are among the disorders due to boron deficiency. Boron deficiency can be alleviated by the application of soluble borates to the soil. In excess quantities, however, borates act as unselective herbicides. Gigantism of several species of plants growing in soil naturally abundant in boron has been reported. It is not yet clear what the precise role of boron in plant life is, but most researchers agree that the element is in some way essential for the normal growth and functioning of apical meristems, the growing tips of plant shoots.

Pure boron exists in at least four crystalline modifications or allotropes. Closed cages containing 12 boron atoms arranged in the form of an icosahedron occur in the various crystalline forms of elemental boron.

Crystalline boron is almost inert chemically at ordinary temperatures. Boiling hydrochloric acid does not affect it, and hot concentrated nitric acid only slowly converts finely powdered boron to boric acid (H3BO3). Boron in its chemical behaviour is nonmetallic.

In nature, boron consists of a mixture of two stable isotopes—boron-10 (19.9 percent) and boron-11 (80.1 percent); slight variations in this proportion produce a range of ±0.003 in the atomic weight. Both nuclei possess nuclear spin (rotation of the atomic nuclei); that of boron-10 has a value of 3 and that of boron-11, 3/2, the values being dictated by quantum factors. These isotopes are therefore of use in nuclear magnetic resonance spectroscopy, and spectrometers specially adapted to detecting the boron-11 nucleus are available commercially. The boron-10 and boron-11 nuclei also cause splitting in the resonances (that is, the appearance of new bands in the resonance spectra) of other nuclei (e.g., those of hydrogen atoms bonded to boron).

Additional Information:

Appearance

Pure boron is a dark amorphous powder.

Uses

Amorphous boron is used as a rocket fuel igniter and in pyrotechnic flares. It gives the flares a distinctive green colour.

The most important compounds of boron are boric (or boracic) acid, borax (sodium borate) and boric oxide. These can be found in eye drops, mild antiseptics, washing powders and tile glazes. Borax used to be used to make bleach and as a food preservative.

Boric oxide is also commonly used in the manufacture of borosilicate glass (Pyrex). It makes the glass tough and heat resistant. Fibreglass textiles and insulation are made from borosilcate glass.

Sodium octaborate is a flame retardant.

The isotope boron-10 is good at absorbing neutrons. This means it can be used to regulate nuclear reactors. It also has a role in instruments used to detect neutrons.

Biological role

Boron is essential for the cell walls of plants. It is not considered poisonous to animals, but in higher doses it can upset the body’s metabolism. We take in about 2 milligrams of boron each day from our food, and about 60 grams in a lifetime. Some boron compounds are being studied as a possible treatment for brain tumours.

Natural abundance

Boron occurs as an orthoboric acid in some volcanic spring waters, and as borates in the minerals borax and colemanite. Extensive borax deposits are found in Turkey. However, by far the most important source of boron is rasorite. This is found in the Mojave Desert in California, USA.

High-purity boron is prepared by reducing boron trichloride or tribromide with hydrogen, on electrically heated filaments. Impure, or amorphous, boron can be prepared by heating the trioxide with magnesium powder.

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