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Jai Ganesh

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Registered: 2005-06-28

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Re: crème de la crème

2439) Cyril N. Hinshelwood

Gist:

Work

During chemical reactions, atoms and molecules regroup and form new constellations. When molecules formed during a reaction readily react with molecules present from the beginning, a chain reaction can occur. Explosions and fire are examples of chain reactions. During the 1930s Cyril Hinshelwood analyzed conditions and sequences of events involved in chain reactions from a theoretical standpoint. Among other things, he found that the theoretical results corresponded with observations of the reaction between hydrogen and oxygen.

Summary

Sir Cyril Norman Hinshelwood (born June 19, 1897, London, Eng.—died Oct. 9, 1967, London) was a British chemist who worked on reaction rates and reaction mechanisms, particularly that of the combination of hydrogen and oxygen to form water, one of the most fundamental combining reactions in chemistry. For this work he shared the 1956 Nobel Prize for Chemistry with the Soviet scientist Nikolay Semyonov.

Hinshelwood obtained his doctorate at the University of Oxford in 1924 and became professor of chemistry there in 1937. After retiring from Oxford in 1964 he became a senior research fellow at Imperial College, London.

About 1930 Hinshelwood began investigating the complex reaction in which hydrogen and oxygen atoms combine to form water. He showed that the products of this reaction help to spread the reaction further in what is essentially a chain reaction.

He next sought to explore molecular kinetics within the bacterial cell. Upon observing the biological responses of bacteria to changes in environment, he concluded that more or less permanent changes in a cell’s resistance to a drug could be induced. This finding was important in regard to bacterial resistance to antibiotic and other chemotherapeutic agents. Hinshelwood was knighted in 1948. His publications include The Kinetics of Chemical Change in Gaseous Systems (1926) and The Chemical Kinetics of the Bacterial Cell (1946).

Details

Sir Cyril Norman Hinshelwood (19 June 1897 – 9 October 1967) was a British physical chemist and expert in chemical kinetics. His work in reaction mechanisms earned the 1956 Nobel Prize in chemistry.

Education

Born in London, his parents were Norman Macmillan Hinshelwood, a chartered accountant, and Ethel Frances née Smith. He was educated first in Canada, returning in 1905 on the death of his father to a small flat in Chelsea where he lived for the rest of his life. He then studied at Westminster City School and Balliol College, Oxford.

Career

During the First World War, Hinshelwood was a chemist in an explosives factory. He was a tutor at Trinity College, Oxford, from 1921 to 1937 and was Dr Lee's Professor of Chemistry at the University of Oxford from 1937. He served on several advisory councils on scientific matters to the British Government.

His early studies of molecular kinetics led to the publication of Thermodynamics for Students of Chemistry and The Kinetics of Chemical Change in 1926. With Harold Warris Thompson he studied the explosive reaction of hydrogen and oxygen and described the phenomenon of chain reaction. His subsequent work on chemical changes in the bacterial cell proved to be of great importance in later research work on antibiotics and therapeutic agents, and his book, The Chemical Kinetics of the Bacterial Cell was published in 1946, followed by Growth, Function and Regulation in Bacterial Cells in 1966. In 1951 he published The Structure of Physical Chemistry. It was republished as an Oxford Classic Texts in the Physical Sciences by Oxford University Press in 2005.

The Langmuir-Hinshelwood process in heterogeneous catalysis, in which the adsorption of the reactants on the surface is the rate-limiting step, is named after him. He was a senior research fellow at Imperial College London from 1964 to 1967.

Awards and honours

In addition to being named the second Dr. Lee's Professor of Chemistry at Oxford, Hinshelwood was elected Fellow of the Royal Society (FRS) in 1929, serving as president from 1955 to 1960. He was knighted in 1948 and appointed to the Order of Merit in 1960. With Nikolay Semenov of the USSR, Hinshelwood was jointly awarded the Nobel Prize in Chemistry in 1956 for his researches into the mechanism of chemical reactions. He was also an elected member of the American Academy of Arts and Sciences, the United States National Academy of Sciences, and the American Philosophical Society.

Hinshelwood was president of the Chemical Society, the Royal Society, the Classical Association, and the Faraday Society, and received numerous awards and honorary degrees. He was elected on 1 January 1960 to honorary membership of the Manchester Literary and Philosophical Society who awarded him its Dalton medal in 1966.

Personal life

Hinshelwood never married. He was fluent in seven classical and modern languages and his main hobbies were painting, collecting Chinese pottery, and foreign literature. As an artist, Hinshelwood painted scenes in Oxford, as well as portraits of Oxford University people including Harold Hartley, his doctoral supervisor, and Herbert Blakiston, the President of Trinity College. The portrait of Hartley is now owned by the Royal Society, and that of Blakiston is owned by Trinity College, as are a number of Hinshelwood's other paintings.

He died, at home, on 9 October 1967. In 1968, his Nobel Prize medal was sold by his estate to a collector, who then sold it in 1976 for $15,000. In 2017, his Nobel Prize medal was sold at auction for $128,000.

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