The diagonals of a parallelogram bisect each other. So y=2x+c must pass through middle of the opposite vertices - (3,2). On substituting, we get c = -4.
Let us say that vertices are (x,y) the angle between two lines from (x,y) to the other 2 vertices should be 90. Which is true if and only if m1 X m2 = -1. Using this and y=2x-4, we get the other vertices as (2,0) and (4,4)